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The collection represents the contacts through two centuries of a group of men and women of high distinction ramifying through the medical, legal and literary worlds. It forms a not unimportant fund of minor historical material, comprising more than a thousand letters from nearly five hundred writers.

The autograph letters are mounted in 10 large volumes: -

1. Letterbook of John Arbuthnot (1667-1735). The most interesting letters are those of Pope and Swift and their circle written in 1714 when the Queen's death involved the destruction of their political hopes. Letterbook of William Hunter (1719-1783). It includes letters from Tobias Smollett the novelist, from Dr. Johnson thanking Hunter for presenting his book to the King, and from Edward Gibbon 'proposing himself the pleasure of attending some of Dr. Hunter's Anatomical lectures.'

2. Hunter and Baillie family letters and reminiscences, including the letters written by John to William Hunter from active service in 1761-62; poems by Sophia Baillie, Jenner family letters.

   3. Letters to Matthew Baillie from the Royal Princesses. Letters of the Bentham family, including three from Jeremy Bentham. Autograph letter collection includes letters from Thomas Carlyle and Charles Dickens. 1735 - 1845

3. Denman family collection; autographs collections of Lady Bell and Dr. William Whewell; letters of John Baron, Edward Jenner's biographer; fragment of unpublished music by Mozart; letters from Joanna Baillie's friends including c.1782-1877

4. Letters to Joanna Baillie includes letters from Sir Walter Scott and Maria Edgeworth. Various dates

5. William Hunter's diplomas, and letters to him, Hunter family documents, and notes on family history compiled by Joanna and Matthew Baillie. Locks of hair and christening caps worn by Hunter family. Various dates

6. Matthew Baillie's letters to William Hunter includes material relating to treatment of George III and to his wife Sophia (Denman) and his diplomas. C. 1783-1823

7. Matthew Baillie's professional correspondence including notes on illness of George III and on labour of Princess Charlotte. Letter to Helen Hunter Baillie from George Peachy re Matthew Baillie's notebooks (1923). 1783-1923

8. Joanna Baillie's letters and papers relating to her plays, sale of her works, mss. of two stories and a comedy, letters from Mrs Sigourney, Henry Siddons, Anne Hunter, Mary Somerville; Agnes Baillie's reminiscences, prescriptions by Matthew Baillie

9. Princess Mary's letters to Baillie concerning the illness of Princess Amelia, Anne Hunter's autograph poems, libretto of Haydn's Creation; account of death of Princess Charlotte.

   The Hunter Baillie collection comprises also a number of manuscript books, the oldest of which is a commonplace book of the early eighteenth century, giving details of family history of the Hunters. Matthew Baillie's notebooks include: -

Journal of a tour in Europe in 1788 and A short memoir of my life, 1818. 'Some brief observations from my own experience upon a considerable number of diseases', in two volumes. n.d. With these are his casebooks, fee-books and other professional notes, including details of his attendance on King George III. Baillie records that his total annual fees mounted from £121 in 1792 to £9,995 in 1815.