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The collection includes two of his diaries (1854 and 1875), letters of condolence on his death and many of his personal letters. Some of the letters pertain to his work in the explosives industry while many are correspondence between him and his social and professional contemporaries: Sir William Armstrong, Sir James Dewar, The Duke of Devonshire, Michael Faraday, Thomas Graham, Carl Haag, A W von Hofmann, William Odling and William Rockerfeller as well as the private secretaries acting on behalf of Queen Victoria and the Prince of Wales (latterly King George V).

Books, pamphlets and folio-size posters on explosives and firearms dating from 1598 to 1920. Many of the pamphlets in the collection relate to the manufacture and use of gunpowder.