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George Duncan Gibb was born in Montreal, Canada, on 25 December 1821. He studied medicine at McGill University and graduated in 1846, being appointed immediately afterwards as Surgeon to the Canadian Militia. He moved to Dublin to pursue his studies, becoming a Licentiate of the Royal College of Surgeons in Ireland. In 1853, Gibb moved to London being at first Physician at St Pancras General Dispensary which he left to take up the post of Assistant Physician to the Westminster Hospital in 1863.
Throughout his stay in London, Gibb added various qualifications to his name, FGS (1855), MRCP (1859), LLD (1864 from Quebec) and most notably 'Sir' which was attached to a supposed baronetcy - a title which he adopted after research into his family history discovered it to be 'vacant'.
Gibb wrote numerous publications on laryngology, his family history, unusual meteorology and Canadian geology. He died on 16 February 1876 from lung disease.