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Born Meerut, India, 1818; educated at St Andrew's Scotland; studied chemistry under Thomas Graham at the Andersonian University of Glasgow, University College, London, Liebig's laboratory at Giessen, Germany; awarded PhD at Giessen, 1841; chemical manager of a calico printing works, 1841; honorary Professor of Chemistry at the Royal Insitution, Manchester, 1843; served on Royal Commission on Health of Towns, 1843; research with Bunsen on the chemistry of blast-furnace gases, 1844; Chemist to the Geological Survey, 1845; reported to Sir Robert Peel on the potato crop in Ireland, 1845; Fellow of the Royal Society, 1848; Special Commissioner for the Great Exhibition, 1850; lecturer on Chemistry at the Government School of Mines, 1851; CB, 1851; Joint Secretary of the Science and Art Department of the Board of Trade, 1853; Inspector General of Government Museums and Schools of Science, 1856; President of the Chemical Society, 1857-1859; Professor of Chemistry at Edinburgh University, 1858-1869; Commissioner for the Exhibition of 1851, 1869; Liberal MP for the Universities of Edinburgh and St Andrews, 1869; Postmaster General in Gladstone's first ministry, 1873-1874; Chairman of Ways and Means, 1880-1883; Deputy Speaker of the House of Commons, 1880-1883; awarded KCB, 1883; Honorary Secretary of the 1851 Commission, 1883-1889; MP for South Leeds, 1885; President of the British Association for the Advancement of Science, 1885; Vice-President of the Council, 1886; Charity Commissioner, 1886; created Baron Playfair of St Andrews, 1892; Lord in Waiting to Queen Victoria, 1892; awarded GCB, 1894; member of the Aged Poor Commission, 1894; died Kensington, London, 1898.
Publications: include Collieries. Report on the gases and explosions in collieries with Sir Henry Thomas De la Beche and Warington Smyth [Shannon, Irish University Press, 1969]; Report on the State of Large Towns in Lancashire (W Clowes & Sons, London, 1845); Bunsen and Playfair's Report to the British Association at Cambridge in 1845, on the gases evolved from iron furnaces with reference to the theory of the smelting of iron, etc edited by B H Brough (London, 1903); On the Chemical Properties of Gold (1853); On Primary and Technical Education. Two lectures, etc (Edinburgh, 1870); On the Organisation of a Teaching Profession [1877]; Subjects of Social Welfare (Cassell & Co, London, 1889); The Evolution of University Extension as a part of Popular Education (1894).